Starting with the basics of JavaScript is a good idea, IMHO.
Read JavaScript: The Good Parts, by Douglas Crockford. Very, very good book.
You should also check out Douglas Crockford's web site.
I also had to come back here and mention this in an update:
Douglas Crockford presented an illuminating talk about JavaScript - past, present, future - at the Microsoft MIX10 conference earlier this year. You'll find the full video for Crockford's talk at Microsoft MIX10 - The Tale of JavaScript. I Mean ECMAScript.